Our Solutions: Testing
UN Transportation Classification Testing for Hazardous Materials

Our laboratories provide essential test data for the dangerous substances you transport.
We conduct the following tests to assess the safety and compliance of hazardous materials for UN Transportation Classification Testing:
- Oxidizing Solids-UN Test O.1
- Readily Combustible Solids or Flammability of Solids-UN Test N.1
- Self Heating Solids-UN Test N.4
- Oxidizing Solids-UN Test O.1
- Readily Combustible Solids or Flammability of Solids-UN Test N.1
- Self Heating Solids-UN Test N.4
Please contact us if you have any customized testing requirements or need assistance with UN Transportation Classification Testing to ensure safe and compliant hazardous material transport.
UN Transportation Classification Testing
Why Transportation Classification Testing is Essential
Transportation Classification Testing is critical for ensuring the safe and compliant transport of hazardous materials. By conducting thorough testing, you can:
- Classify hazardous materials according to UN standards, ensuring correct labeling and safe handling during transportation.
- Evaluate transport risks such as oxidation, flammability, and self-heating potential to prevent accidents.
- Ensure compliance with both UN regulations, reducing the risk of penalties, delays, and safety hazards.
- Verify packaging and containment systems to prevent leaks, spills, or environmental damage during transit.
Integrating Transportation Classification Testing into your safety protocols helps protect your workforce, the public, and the environment, ensuring the secure transport of hazardous materials.
Discover Our Range of UN Transportation Classification Testing Solutions
Ensuring the safe transport of hazardous materials and protecting your people, workplaces, and the environment from transportation risks is critical. Proper UN Transportation Classification Testing helps identify, assess, and mitigate risks associated with transporting dangerous goods, preventing incidents such as leaks, spills, or environmental hazards.
Our UN Transportation Classification Testing services provide comprehensive solutions to help you accurately classify hazardous materials and ensure compliance with UN regulations, with a turnaround time of 7-10 business days from receipt of the sample.
Learn more about our testing services below and contact us for a free, no-obligation consultation today.
Oxidizing Solids - UN Test O.1
Recommendations on the Transport of Dangerous Goods, UN Manual of Test & Criteria – UN Test O.1
This test is primarily conducted for the purposes of transportation. Mixtures of a reference oxidizer (potassium bromate) / cellulose (fuel) and the mixtures of the substance and cellulose (fuel) that are to be tested are prepared in specified ratios. Using a conical funnel, the mixtures are formed into a truncated conical pile which is covered by a looped ignition wire that rests on a low heat conducting plate. Power is then applied to the ignition wire and is maintained for the duration of the test.
A recorded burning time is taken from when the power is switched on, to when the main reaction (e.g. flame, incandescence or glowing combustion) ends. This test is performed on the cellulose ratio five times. Each substance is also subject to five tests, with each reference mixture ratio required to make a packing group assignment to determine if the substance should not be classified in Division 5.1. The test method is identical to that detailed within CLP/GHS regulatory procedures and therefore, data gathered can be used for both applications.
Materials that are classified for transportation, such as oxidizing solids, are usually based on either guess work or comparative studies. These are often incorrect and large costs associated with classified oxidized materials can be avoided. If a product contains a known oxidizing constituent, it doesn’t simply mean the blend should also be classified.
Readily Combustible Solids or Flammability of Solids - UN Test N.1
Recommendations on the Transport of Dangerous Goods, UN Manual of Test & Criteria – UN Test N.1
The test is conducted to determine whether a solid material should be classified, for transportation as a flammable or readily combustible substance of UN Class 4, Division 4.1. The same test technique applies for classification under CLP as a Flammable Solid (H.228)
A powder strip is formed using a triangular cross sectioned mold, onto a heat resistant, non-porous plate. Using a butane flame, one end of the strip is ignited and the initially the time taken to burn over a marked 200 mm length is recorded.
If the time taken is equal to or less than 120 s then further trials are conducted over fresh powder strips and the burning rate over a length of 100 mm measured.
If the time taken is equal to or less than 45 s (2.2 mm.s-1) then the material is classified as a ‘Flammable or Combustible Solid, of UN Class 4, Division 4.1. During the 100 mm trials, a section of the material past the 100 mm mark is wetting and observations are made to whether the wetted zone, stops flame propagation for at least 4 minutes.
If the wetted zone fails to stop propagation the material is designated to packing group 2, if it succeeds, a packing group 3 designation is given. The test method is identical to that detailed within CLP/GHS regulatory procedures and therefore data gathered can be used for both applications.
Materials that are being classified for transport as a flammable solid, based on either guess work or comparative studies are often incorrect and the large costs associated with classified flammable materials can be avoided. Because a product, contains a known flammable constituent, doesn’t simply mean the blend should also be classified.
Self Heating Solids – UN Test N.4
Recommendations on the Transport of Dangerous Goods, UN Manual of Test & Criteria – UN Test N.4
The test is conducted to determine whether a solid material should be classified, for transportation as a Self-Heating Solid of UN Class 4, Division 4.2. The same test technique applies for classification under CLP as a Self-Heating Solid (H.251 & H.252)
The sample, in its commercial form is filled to the brim of the test basket and the basket tapped several times. More material is added, if the material is seen to have settled. The basket is housed in the mesh cover and placed into the center of a preheated, hot air, circulating oven, set to the required test temperature.
The initial test is conducted using a 100 mm cube sample, at a temperature of 140 °C. The sample temperature and oven temperature are continually monitored, using inconel sheathed thermocouples over a test period of 24 h (unless ignition is detected earlier). If ignition is not observed, then the material is not classified as a self-heating solid. If ignition is observed, then the material is classified, and further testing is required to designate the correct packing group and/or classification exemption conditions.
All though a material maybe self-heating, if transported within specified volume restrictions, exceptions can be made and therefore huge costs avoided. These exemptions can only be determined through testing.
Can't find the UN Transportation Classification Testing you need?
Get in touch with one of our experts to learn how our UN Transportation Classification Testing services can help you ensure the safe transport of hazardous materials.
From classifying hazardous materials for compliance with UN regulations to evaluating risks such as flammability, self-heating, and oxidation, we provide comprehensive transportation classification testing solutions for any dangerous substance. Whether it’s determining appropriate packaging, labeling, or assessing material risks, we help you ensure the safety and compliance of your hazardous goods during transport.
The Sigma-HSE Advantage
From reaction calorimetry testing to oxidizing solids – UN Test O.1, Sigma-HSE is your single solution provider for transportation classification testing. Our dedicated team of experts are committed to helping you ensure and maintain compliance.
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